|
|
ceramide + H2O <=> sphingosine + fatty_acid
|
3.5.1.23
ceramidase
|
–
|
|
BRENDA:
BR19241;
BS116225
KEGG:
R01493;
R01494
MetaCyc:
CERAMIDASE-RXN;
RXN-11375
SABIO-RK:
1667
|
|
|
|
palmitoyl-CoA + NADP+ <=> trans-2-hexadecenoyl-CoA + NADPH + H+
|
1.3.1.38
trans-2-enoyl-CoA reductase (NADPH)
1.3.1.8
acyl-CoA dehydrogenase (NADP+)
|
–
–
|
|
BRENDA:
BS258627
KEGG:
R01278
MetaCyc:
RXN-14194
SABIO-RK:
1494
|
|
|
|
2-trans-hexadecenal + NAD+ + H2O <=> (2E)-hexadecenoate + NADH + H+
|
1.2.1.3
aldehyde dehydrogenase (NAD+)
|
–
|
|
MetaCyc:
RXN-16656
|
|
|
|
(2E)-hexadecenoate + CoA + ATP <=> trans-2-hexadecenoyl-CoA + diphosphate + AMP
|
6.2.1.3
long-chain-fatty-acid---CoA ligase
|
–
|
|
MetaCyc:
RXN-19751
|
|
|
|
sphingosine_1-phosphate + H2O <=> sphingosine + phosphate
|
3.1.3
3.1.3.4
phosphatidate phosphatase
|
–
–
|
|
BRENDA:
BS380760
KEGG:
R06521
MetaCyc:
RXN3DJ-25
|
|
|
|
sphingosine_1-phosphate <=> 2-trans-hexadecenal + Phosphoethanolamine
|
4.1.2
4.1.2.27
sphinganine-1-phosphate aldolase
4.3.2
|
–
–
–
|
|
BRENDA:
BS416810
KEGG:
R06516
MetaCyc:
RXN3DJ-11230
|
|
|
|
hexadecanal + NADP+ <=> 2-trans-hexadecenal + NADPH + H+
|
1.3.1.27
2-hexadecenal reductase
|
–
|
|
BRENDA:
BR36808
KEGG:
R02463
MetaCyc:
2-HEXADECENAL-REDUCTASE-RXN
|
|
|
|
sphingosine + ATP <=> H+ + sphingosine_1-phosphate + ADP
|
2.7.1.91
sphingosine kinase
|
–
|
|
BRENDA:
BR44314
KEGG:
R01926
MetaCyc:
RXN3DJ-11417
SABIO-RK:
1980
|
|
|
|
hexadecanal + NAD+ + H2O <=> fatty_acid + NADH + H+
|
1.2.1.3
aldehyde dehydrogenase (NAD+)
1.2.1.47
4-trimethylammoniobutyraldehyde dehydrogenase
1.2.1.48
long-chain-aldehyde dehydrogenase
1.2.1.5
aldehyde dehydrogenase [NAD(P)+]
|
–
–
–
–
|
|
BRENDA:
BR36783
KEGG:
R01704;
R02039
MetaCyc:
LONG-CHAIN-ALDEHYDE-DEHYDROGENASE-RXN;
RXN-16655
SABIO-RK:
1816
|
|
|
|
fatty_acid + CoA + ATP <=> stearoyl-CoA + AMP + diphosphate
|
1.13.12.7
firefly luciferase
6.2.1.12
4-coumarate---CoA ligase
6.2.1.3
long-chain-fatty-acid---CoA ligase
6.2.1.30
phenylacetate---CoA ligase
6.2.1.B3
|
–
–
–
–
–
|
|
BRENDA:
BR82;
BS287
KEGG:
R00390;
R01280
MetaCyc:
RXN-16380;
RXN-7904;
RXN-9623
SABIO-RK:
10953;
1496
|
|